Natasha Ek Paheli web series premiere episode begins with a man Suraj Kadam in a sinister dream, a nightmare in all probability. He sees himself in the mirror, instructing himself to wear slippers while a girl forcefully injects a syringe in his body. Next morning, the man visits his doctor who also happens to have saved him in the past. The man is a police officer who begins to narrate his story of how his life went from being perfect to in shambles. The man Suraj, in a flashback, is shown spending quality time with his beautiful girlfriend Simmi. He soon gets called to a crime spot where a hotelier Rishabh Mehta is murdered. Another person present in the lavish home is Natasha Kamra, a superstar of the adult entertainment industry. The cop wants to take her statement but her lawyer tries to persuade him otherwise. Sapna Biswas from CID is also entrusted with the task of solving this case with the cop. Sapna and the cop visit the morgue and get their hands on more details about how Rishabh was killed. Later, a CCTV footage reveals a masked man entering the deceased’s residential premises. Suraj’s friends are busy teasing him that he would not get to work with such a good-looking suspect, Natasha. Just then, Natasha enters and justifies it is this very treatment to an adult movie star that deterred her from visiting the police station. Suraj tells her he’d record her statement at her home. Natasha is the only one who was present at the time of Rishabh’s murder. Are things as simple as they seem? What is the connection between Suraj’s nightmare and the case?